Experimental Study of Reductive Elimination of H2 from Rhodium Hydride Species
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https://figshare.com/articles/dataset/Experimental_Study_of_Reductive_Elimination_of_H_sub_2_sub_from_Rhodium_Hydride_Species/2528737
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A RhIII monohydride terpyridine complex undergoes reductive elimination of H2 in CH3CN to form a dinuclear RhII complex with a metal–metal bond. Kinetic studies have revealed that the conversion from the monohydride species to the dinuclear species with evolution of H2 obeys first-order kinetics and have determined the kinetic deuterium isotope effect value to be 2.0. We discuss the mechanism for the reductive elimination of H2 from rhodium hydride species.
创建时间：
2016-02-21
