Rhodium-Catalyzed Oxidative Coupling of Benzoic Acids with Terminal Alkynes: An Efficient Access to 3‑Ylidenephthalides
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Oxidative_Coupling_of_Benzoic_Acids_with_Terminal_Alkynes_An_Efficient_Access_to_3_Ylidenephthalides/3123511
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Herein we disclose the first example of transition-metal-catalyzed oxidative coupling/annulation of simple benzoic acids with terminal alkynes via C–H activation. A range of aromatic carboxylic acids and terminal alkynes have been found to be viable substrates in this reaction, providing a simple and efficient method for the synthesis of diverse 3-ylidenephthalides with complete Z selectivity.
创建时间：
2016-05-17
