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Stabilization of Imidosamarium(III) Cubane by Amidinates

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Stabilization_of_Imidosamarium_III_Cubane_by_Amidinates/2842360
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An imidosamarium(III) cubane has been prepared from the reductive cleavage of azobenzene by a divalent samarium bis(amidinate) complex, indicating that the “spectrator” bis(amidinate) and the resulting imido ligands help to stabilize the cubane framework. The cubane-type imido cluster is a novel unit in lanthanide chemistry.
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2016-02-26
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