Cerium(III) and Neodymium(III) Amides Derived from a Chelating 2-Pyridyl Amido Ligand
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https://figshare.com/articles/dataset/Cerium_III_and_Neodymium_III_Amides_Derived_from_a_Chelating_2-Pyridyl_Amido_Ligand/3611718
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资源简介：
Homoleptic Ce(III) and Nd(III) triamides [LnL3] [Ln = Ce (1) or Nd
(2)] and the heterobimetallic amide−alkoxide derivatives [LnL2(μ-OBut)2M(tmeda)] [Ln = Ce, M = Na (3); Ln = Nd, M = Na (4);
Ln = Nd, M = K (5)] supported by the bulky [N(SiButMe2)(2-C5H3N-6-Me)]- ligand (L-) have been successfully synthesized
and characterized. Complexes 1−3 and 5 show a high activity
toward the ring-opening polymerization of ε-caprolactone.
创建时间：
2016-08-17
