Isothermal Vapor Liquid Equilibrium for 2-Methylpropene + Methanol, + 1-Propanol, + 2-Propanol, + 2-Butanol, and + 2-Methyl-2-propanol Binary Systems at 364.5 K

Vapor?liquid equilibrium data were measured using an automatic static total pressure apparatus for binary mixtures of 2-methylpropene + methanol, + 1-propanol, + 2-propanol, + 2-butanol, and + 2-methyl-2-propanol at 364.5 K. The measured p, T, z data were fitted against Legendre polynomials and reduced using Barker's method to obtain phase equilibrium data. In addition to Legendre polynomials, binary interaction parameters were also optimized for Wilson, UNIQUAC, and NRTL activity coefficient models. All binary data showed a positive deviation from the Raoult's law. In addition, azeotropic behavior was observed for the 2-methylpropene + methanol binary mixture.