A Trinuclear EMAC-Type Molecular Wire with Redox-Active Ferrocenylacetylide “Alligator Clips” Attached
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https://figshare.com/articles/dataset/A_Trinuclear_EMAC_Type_Molecular_Wire_with_Redox_Active_Ferrocenylacetylide_Alligator_Clips_Attached/3340261
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资源简介：
Reaction of lithium ferrocenylacetylide (LiFcA) with [Co3(dpa)4(NCCH3)2](PF6)2 (dpa = 2,2‘-dipyridylamide) in acetonitrile solution yields the bis-ferrocenylacetylide EMAC (extended metal atom chain)
Co3(dpa)4(FcA)2 in good yield and excellent purity. The
crystal structure features a distinctly unsymmetrical
tricobalt chain with a Co−Co bond distance of 2.3091(8) Å and a longer Co···Co separation of 2.5208(9) Å.
Cyclic and differential pulse voltammetry show that the
two Fe2+/3+ oxidations occur nearly simultaneously, with
a ΔE1/2 of 71 mV.
创建时间：
2004-05-10
