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Synthesis, Resolution, and Absolute Configuration of Chiral 4,4′-Bipyridines

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https://figshare.com/articles/dataset/Synthesis_Resolution_and_Absolute_Configuration_of_Chiral_4_4_Bipyridines/2539645
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资源简介:
A chiral polyhalogenated 4,4′-bipyridine derivative is described allowing an easy access to a new family of chiral 4,4′-bipyridines by site-selective cross-coupling reactions. The absolute configurations of all the HPLC separated enantiomers were determined by X-ray diffraction and electronic circular dichroism coupled with time-dependent density functional theory calculations.
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2012-03-16
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