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A New Nine-Membered Triphosphorus Macrocycle

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/A_New_Nine-Membered_Triphosphorus_Macrocycle/3762633
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The first nine-membered triphosphorus macrocycles based on an o-benzobis(ethane-1,2-diyl) core have been prepared in high yield by the coupling of 1,2-diphosphinobenzene with trivinylphosphine on a cationic (η5-pentamethylcylopentadienyl)iron(II) template. Hydrogenation of the vinyl function followed by alkylation of the secondary phosphines gives the coordinated triethyl macrocycle, which has been structurally characterized.
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2016-08-26
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