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Intramolecular Interactions in Crystals of Tris(2,6-diisopropylphenoxy)silanethiol and Its Sodium Salts

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https://figshare.com/articles/dataset/Intramolecular_Interactions_in_Crystals_of_Tris_2_6_diisopropylphenoxy_silanethiol_and_Its_Sodium_Salts/2560363
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资源简介:
Hydrolytically stable silanethiol tris­(2,6-diisopropylphenoxy)­silanethiol (TDST) has been synthesized and reacted with sodium metal. In solid state TDST exhibits π-interactions between the S–H unit and the π-system of the arene, replaced by cation-π interactions in its sodium salts. The interactions are documented by crystal structures and FT-IR spectroscopy.
创建时间:
2016-02-22
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