Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal Alkynes
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https://figshare.com/articles/dataset/Rh-Catalyzed_Anti-Markovnikov_Hydrocyanation_of_Terminal_Alkynes/5025029
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资源简介：
We
report the first highly stereo- and regioselective hydrocyanation
of terminal alkynes to furnish E-configured alkenyl
nitriles. Acrylonitriles can be accessed on gram scale with broad
substrate scope and functional group tolerance. The hydrocyanation
reaction employs acetone cyanohydrin as a practical alternative to
HCN gas.
创建时间：
2017-05-19
