Enantioselective Rhodium-Catalyzed Arylation of Cyclic N‑Sulfamidate Alkylketimines: A New Access to Chiral β‑Alkyl-β-aryl Amino Alcohols
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https://figshare.com/articles/dataset/Enantioselective_Rhodium_Catalyzed_Arylation_of_Cyclic_i_N_i_Sulfamidate_Alkylketimines_A_New_Access_to_Chiral_Alkyl_aryl_Amino_Alcohols/2281233
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The enantioselective rhodium-catalyzed 1,2-addition of arylboronates to cyclic N-sulfamidate alkylketimines was developed. With a rhodium/diene complex as catalyst, high enantioselectivity and broad functional group tolerance were observed. The resulting sulfamidates can easily be converted into chiral β-alkyl-β-aryl amino alcohols.
创建时间：
2016-02-17
