Reaction of Bis(pentafluorophenyl)borane with Methylidyne Complexes: Synthesis and Characterization of a Cationic Tungsten(VI) Borylalkylidyne Hydride
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Reaction_of_Bis_pentafluorophenyl_borane_with_Methylidyne_Complexes_Synthesis_and_Characterization_of_a_Cationic_Tungsten_VI_Borylalkylidyne_Hydride/3351598
下载链接
链接失效反馈官方服务：
资源简介：
Reaction of the tungsten methylidyne complexes (dmpe)2W(X)⋮CH (X = Cl, OTf) with HB(C6F5)2
yields zwitterionic compounds upon electrophilic attack
of the methylidyne ligand, in which the methylidyne
hydrogen is strongly α-agostic (X = Cl) or is transferred
to the tungsten center (X = OTf). Removal of hydride
from the coordinated HB(C6F5)2 with [Ph3C]+[B(C6F5)4]-
gives a cationic borylalkylidyne hydride species.
创建时间：
2004-02-02
