Generation of Fullerenyl Cation (EtO)<sub>2</sub>P<sup>+</sup>(OH)CH<sub>2</sub>−C<sub>60</sub><sup>+</sup> from RC<sub>60</sub>−H and from RC<sub>60</sub>−C<sub>60</sub>R (R = CH<sub>2</sub>P(O)(OEt)<sub>2</sub>)
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资源简介：
A novel fullerenyl cation (EtO)2P+(OH)CH2−C60+ was generated by simply dissolving the monofunctionalized hydrofullerene RC60−H or singly bonded dimer RC60−C60R (R = CH2P(O)(OEt)2) in oxidizing acids such as H2SO4 and FSO3H. The cation was also formed in CH2Cl2 by one-electron oxidation with aminium radical cation and was used for further functionalization of C60.
创建时间：
2016-05-06
