Deduced molecular weights from the differently charged peaks in the spectra of the starting material, non-digested oxidized synthetic hPTH(1–84)ox (Fig. 1B), and the eluate from the affinity column (Fig. 3B).
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The molecular masses correspond to values shifted by +16, +32, +48, +64 Da caused by methionine oxidation (sulfoxide, +16 Da and sulfone, +32 Da for each residue, and combinations thereof, maximal+64 Da) and by +80 Da for the additional oxidation of tryptophan 23.
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2015-12-02



