Transition Metal Complexes of α-keto Stabilized Sulfonium Ylides: Linear in Contrast to Bridging Structure in Silver(I) Complexes
收藏DataCite Commons2020-09-04 更新2024-07-25 收录
下载链接：
https://tandf.figshare.com/articles/dataset/Transition_Metal_Complexes_of_945_keto_Stabilized_Sulfonium_Ylides_Linear_in_Contrast_to_Bridging_Structure_in_Silver_I_Complexes/1121497/1
下载链接
链接失效反馈官方服务：
资源简介：
The reactions of α-keto stabilized sulfonium ylide (Me)<sub>2</sub>SCHC(O)C<sub>6</sub>H<sub>4</sub>-m-NO<sub>2</sub> (<b>Y<sub>1</sub></b>) with HgX<sub>2</sub> (X = Cl (<b>1</b>), Br (<b>2</b>) and I (<b>3</b>)) in equimolar ratios and CdCl<sub>2</sub>.H<sub>2</sub>O (<b>4</b>) in 1:2 molar ratio using methanol as a solvent lead to binuclear Hg(II) complexes and a polymeric Cd(II) organic-inorganic hybrid. Furthermore, from the reaction of sulfonium ylides (<b>Y<sub>1</sub></b>), (Me)<sub>2</sub>SCHC(O)C<sub>6</sub>H<sub>4</sub>-p-NO<sub>2</sub> (<b>Y<sub>2</sub></b>) and (Me)<sub>2</sub>SCHC(O)C<sub>6</sub>H<sub>4</sub>-p-OMe (<b>Y<sub>3</sub></b>) with AgTfO in 2: 1 molar ratio using dichloromethane as a solvent, [Ag(Y<sub>n</sub>)<sub>2</sub>]TfO (n = 1 (<b>5</b>), n = 2 (<b>6</b>), n = 3 (<b>7</b>)) complexes were obtained. Single crystal X-ray diffraction analysis reveals the presence of linear structure for <b>5</b>. Characterization of the obtained compounds was also performed by elemental analysis, IR, <sup>1</sup>H- and <sup>13</sup>C- NMR.
提供机构：
Taylor & Francis
创建时间：
2016-01-19
