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Photoactivation of Ruthenium Olefin Metathesis Initiators

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Photoactivation_of_Ruthenium_Olefin_Metathesis_Initiators/2833327
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UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro−trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.
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2016-02-26
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