GIb04a 1948-2003.xlsx

An actively growing speleothem sampled from New St. Michaels Cave in
2004 is composed of paired laminae consisting of light columnar calcite and a darker microsparitic calcite. Stable isotope analysis of samples
micromilled in 100 μm steps at the equivalent of bi-monthly intervals reveals fabric-correlated annual cycles in carbon isotopes, oxygen isotopes
and trace elements responding to seasonal changes in cave microclimate, hydrology and ventilation patterns. Calcite δ13C values reach a minimum
in the light columnar fabric and evidence from trace element behaviour and cave monitoring indicates that this grows under cave ‘winter’
conditions of highest pCO2, whereas the dark microsparitic calcite, characterised by elevated δ13C and δ18O values grows under low ‘summer’
pCO2 conditions. Drip water δ13CDIC reaches a minimum in March–April, at which time the attenuated δ18O signal becomes most representative
of winter precipitation. An age model based on cycle counting and the position of the 14C bomb carbon spike yields a precisely dated winter
oxygen isotope proxy of cave seepage water for comparison with the GNIP and instrumental climate record for Gibraltar. The δ18O characteristics
of calcite deposited from drip water representing winter precipitation for each year can be derived from the seasonally resolved record and allows
reconstruction of the δ18O drip water representing winter precipitation for each year from 1951–2004. These data show an encouraging level of
correspondence (r2 =0.47) with the δ18O of rainfall falling each year between October and March and on a decadal scale the δ18O of reconstructed
winter drip water mirrors secular change in mean winter temperatures.