Construction of Erythrinane Skeleton via Pd(0)-Catalyzed Intramolecular Dearomatization of para-Aminophenols
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https://figshare.com/articles/dataset/Construction_of_Erythrinane_Skeleton_via_Pd_0_Catalyzed_Intramolecular_Dearomatization_of_i_para_i_Aminophenols/2239519
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A novel Pd(0)-catalyzed intramolecular arylative dearomatization of para-aminophenol derivatives is described. In the presence of 1.25 mol % [Pd(C3H5)Cl]2 and 3.75 mol % RuPhos, the arylative dearomatization reaction proceeds smoothly for a broad range of substrates, offering an efficient synthetic route to erythrinane derivatives in excellent yields.
创建时间：
2016-02-16
