Ni-Catalyzed 1,2-Acyl Migration Reactions Triggered by C–C Bond Activation of Ketones
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https://figshare.com/articles/dataset/Ni-Catalyzed_1_2-Acyl_Migration_Reactions_Triggered_by_C_C_Bond_Activation_of_Ketones/11637807
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资源简介：
A Ni-catalyzed
1,2-acyl migration triggered by C–C bond
cleavage was developed. The process of 1,2-acyl migration followed
by olefin isomerization provides a convenient access to α,β-unsaturated
ketones, which are well-known building blocks in organic synthesis.
Experimental and computational studies show that the selective β-hydride
elimination and Ni-hydride reinsertion play an essential role in this
reaction.
创建时间：
2019-11-06
