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A Light-Induced Vinylogous Nazarov-Type Cyclization

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/A_Light-Induced_Vinylogous_Nazarov-Type_Cyclization/3426035
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The first examples of a photochemically induced vinylogous Nazarov-type cyclization forming a cycloheptadienone core are described. The reaction can be included in a three-step cascade consisting of a photochemical isoxazole–azirine ring contraction, cobalt­(II)-catalyzed ring expansion, and the photochemical cyclization. Furthermore, the first representative of the hitherto unknown 1-azatricyclo­[2.2.0.02,6]­hexanes has been identified as a side product of the azirine formation.
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2016-06-27
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