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Nonamer Water Cluster Encapsulated in a Heterometallic Supramolecular Complex

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Nonamer_Water_Cluster_Encapsulated_in_a_Heterometallic_Supramolecular_Complex/2708881
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A crownlike nonamer water cluster has been observed in the heterometallic supramolecular complex {[Cu(eda)2(H2O)2]3·[Ag6(mna)6]·9H2O} (1), which is built from one anionic hexanuclear silver cluster [Ag6(mna)6]6− and three mononulear [Cu(eda)2(H2O)2]2+ cations (H2mna = 2-mercaptonicotinic acid, eda = ethylenediamine). Moreover, the thermogravimetric curve, UV−vis absorption, and photoluminescence spectra of 1 were discussed.
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2016-02-24
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