Facile Reversibility by Design: Tuning Small Molecule Capture and Activation by Single Component Frustrated Lewis Pairs
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https://figshare.com/articles/dataset/Facile_Reversibility_by_Design_Tuning_Small_Molecule_Capture_and_Activation_by_Single_Component_Frustrated_Lewis_Pairs/2054253
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资源简介：
A series of single component FLPs
has been investigated for small
molecule capture, with the finding that through tuning of both the
thermodynamics of binding/activation and the degree of preorganization
(i.e., ΔS⧧) reversibility
can be brought about at (or close to) room temperature. Thus, the
dimethylxanthene system {(C6H4)2(O)CMe2}(PMes2)(B(C6F5)2): (i) heterolytically cleaves dihydrogen to give an equilibrium
mixture of FLP and H2 activation product in solution at
room temperature and (ii) reversibly captures nitrous oxide (uptake
at room temperature, 1 atm; release at 323 K).
创建时间：
2015-12-17
