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New Synthesis of Benzothiazines and Benzoisothiazoles Containing a Sulfoximine Functional Group

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https://figshare.com/articles/dataset/New_Synthesis_of_Benzothiazines_and_Benzoisothiazoles_Containing_a_Sulfoximine_Functional_Group/3305740
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The reaction of S-2-bromophenyl-S-methylsulfoximine with terminal alkynes in the presence of a palladium catalyst resulted in the formation of both 1,2-benzothiazines and 1,2-benzoisothiazoles. A preference for the former was seen with alkylalkynes, while the latter were preferentially formed with alkynylarenes.
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2005-01-06
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