Total Synthesis of Rubriflordilactone A
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https://figshare.com/articles/dataset/Total_Synthesis_of_Rubriflordilactone_A/2231284
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资源简介:
The first and asymmetric total synthesis
of rubriflordilactone
A, a bisnortriterpenoid isolated from Schisandra rubriflora, has been accomplished in a convergent manner. Two enantioenriched
fragments were forged together to give a functionalized cis-triene. A 6π-electrocyclization/aromatization sequence assembled
the penta-substituted arene, and a formal vinylogous Mukaiyama aldol
reaction introduced the butenolide side chain.
创建时间:
2016-02-16



