Enantioselective Synthesis and Structure Revision of Solandelactone E
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_and_Structure_Revision_of_Solandelactone_E/3031522
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资源简介:
The first total synthesis of solandelactone E has been achieved by a novel and convergent strategy that required 23 steps. The synthesis features a diastereoselective acetal-directed cyclopropanation of an electron-deficient diene, a Sharpless asymmetric dihydroxylation, and a [2,3]-sigmatropic rearrangement of a selenoxide intermediate.
创建时间:
2016-02-29



