Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design
收藏Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Diamondoid_Hydrazones_and_Hydrazides_Sterically_Demanding_Ligands_for_Sn_S_Cluster_Design/2306335
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A series of new adamantane and diamantane hydrazides was synthesized and coupled with organo-functionalized Sn/S clusters of the general type [R1Sn4S6] (R1 = CMe2CH2COMe) to form diamondoid-decorated Sn/S clusters. The new ligand precursors as well as the resulting hybrid compounds were analyzed by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction, and first insights were gained in the installation of sterically highly demanding and at the same time rigid mono-, di-, and trifunctionalized diamondoid ligands on tetrelchalcogenide cages.
创建时间：
2016-02-17
