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Intramolecular Si−Si Bond Activation by the Iron Carbonyl Unit in an (η<sup>4</sup>-Silole)tricarbonyliron Complex

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NIAID Data Ecosystem2026-03-06 收录
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Intramolecular activation of the Si−Si bond linked to an η4-silole ligand by a metal center was observed when 1,1-bis(trimethylsilyl)tetraphenylsilole was heated with Fe(CO)5 in refluxing p-xylene, to produce η4-(1-trimethylsilyl-1-methyltetraphenylsilole)Fe(CO)3 as the final product.

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2008-05-26
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