Synthetic Strategy toward the C44–C65 Fragment of Mirabalin
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https://figshare.com/articles/dataset/Synthetic_Strategy_toward_the_C44_C65_Fragment_of_Mirabalin/2301319
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A convergent and flexible stereoselective synthesis of one isomer of the C44–C65 fragment of mirabalin is described. The key steps include organocatalytic aldolization, ruthenium-catalyzed asymmetric hydrogenation, amide formation, Marshall stereoselective allenylation, and the Nozaki–Hiyama–Kishi reaction.
创建时间:
2016-02-17



