Regiodivergent Hydration–Cyclization of Diynones under Gold Catalysis
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https://figshare.com/articles/dataset/Regiodivergent_Hydration_Cyclization_of_Diynones_under_Gold_Catalysis/12946895
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资源简介：
Skipped diynones, efficiently prepared
from biomass-derived ethyl
lactate, undergo a tandem hydration–oxacyclization reaction
under gold(I) catalysis. Reaction conditions have been developed for
a switchable process that allows selective access to 4-pyrones or
3(2H)-furanones from the same starting diynones.
Further application of this methodology in the total synthesis of
polyporapyranone B was demonstrated.
创建时间：
2020-09-11
