Studies toward the Synthesis of the Epoxykinamycin FL-120B′: Discovery of a Decarbonylative Photocyclization
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https://figshare.com/articles/dataset/Studies_toward_the_Synthesis_of_the_Epoxykinamycin_FL_120B_Discovery_of_a_Decarbonylative_Photocyclization/2521840
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Photo-Friedel–Crafts acylation of a naphthoquinone was attempted in an effort to access a diazobenzofluorenone en route to the epoxykinamycin natural product FL-120B′. Photoirradiation of the naphthoquinone substrate which resulted in the unexpected formation of a tetracyclic naphthofuran via a decarbonylative photocyclization process is described.
创建时间：
2016-02-20
