Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes
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https://figshare.com/articles/dataset/Nickel-Catalyzed_Asymmetric_Reductive_Cross-Coupling_To_Access_1_1-Diarylalkanes/4875149
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资源简介：
An asymmetric Ni-catalyzed
reductive cross-coupling of (hetero)aryl
iodides and benzylic chlorides has been developed to prepare enantioenriched
1,1-diarylalkanes. As part of these studies, a new chiral bioxazoline
ligand, 4-heptyl-BiOX (L1), was developed in order to
obtain products in synthetically useful yield and enantioselectivity.
The reaction tolerates a variety of heterocyclic coupling partners,
including pyridines, pyrimidines, indoles, and piperidines.
创建时间：
2017-04-14
