Constructing Crystalline Heterometallic Indium–Organic Frameworks by the Bifunctional Method
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https://figshare.com/articles/dataset/Constructing_Crystalline_Heterometallic_Indium_Organic_Frameworks_by_the_Bifunctional_Method/2190658
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资源简介：
In
this work, we systematically report four indium–organic
framework (InOF) crystals, which comprise the In(CO2)4 monomer for [InCu(inc)4](NO3) (InOF-5) and [Me2NH2]2[In2(Cu4I4)(pdc)4] (InOF-6), the In(OH)(CO2)2 chain for
[In2(Cu4I4)(OH)2(nia)4] (InOF-7), and In3O(CO2)6 clusters for [(In3O)2(Cu4I4)3(nia)12(H2O)6](NO3)2 (InOF-8).
With the help of the ligand-oriented bifunctional method, a series
of novel heterometallic indium–organic frameworks can be easily
achieved through the way the pyridyl N-affinitive sites connect to
Cu-based units and the COO–-affinitive sites to
In(III) centers. This new strategy will
open the door to the construction of multifunctional and heterometallic
InOF materials.
创建时间：
2016-02-14
