Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives
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https://figshare.com/articles/dataset/Gold-Catalyzed_Reactions_of_Enynals_with_Alkenes_for_Synthesis_Binaphthyl_Derivatives/25620544
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A PPh3Au[B(C6F5)4]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o-Quinodimethane (o-QDM) intermediate’s extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
