Synthesis and Reactivity of New Bis(N-heterocyclic carbene) Iridium(I) Complexes
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https://figshare.com/articles/dataset/Synthesis_and_Reactivity_of_New_Bis_N_heterocyclic_carbene_Iridium_I_Complexes/2360572
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资源简介：
New
complexes of the type trans-[IrCl(η2-COE)(NHC)2] (COE = cis-cyclooctene;
NHC = N-heterocyclic carbene) have been prepared in one step from
the reaction of ca. 4 equiv of NHC or [AgCl(NHC)] with [IrCl(η2-COE)2]2 in benzene. These new complexes
have been characterized by techniques including NMR and IR spectroscopy,
X-ray crystallography, and elemental analysis. Exposing trans-[IrCl(COE)(IiPrMe)2] to CO yielded trans-[IrCl(CO)(IiPrMe)2], which is the only bis(NHC) analogue
of Vaska’s complex trans-[IrCl(CO)(PPh3)2] known to date. The synthesis of trans-[Ir(CO)(IiPrMe)2(R)] (R = MeO, PhCC, OSiPh3, O2CPh) complexes
has been achieved via deprotonation reactions involving the new hydroxide
species trans-[Ir(OH)(CO)(IiPrMe)2].
创建时间：
2016-02-18
