Surprising Coordination for Plutonium in the First Plutonium(III) Borate
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Surprising_Coordination_for_Plutonium_in_the_First_Plutonium_III_Borate/2681116
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The first plutonium(III) borate, Pu2[B12O18(OH)4Br2(H2O)3]·0.5H2O, has been prepared by reacting plutonium(III) with molten boric acid under strictly anaerobic conditions. This compound contains a three-dimensional polyborate network with triangular holes that house the plutonium(III) sites. The plutonium sites in this compound are 9- and 10-coordinate and display atypical geometries.
创建时间：
2016-02-23
