Gold-Catalyzed Oxidative Coupling of Terminal Alkynes and Borane Adducts: Efficient Synthesis of α‑Boryl Ketones
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Herein, we report a gold-catalyzed oxidative coupling reaction of terminal alkynes and borane adducts for the synthesis of α-boryl carbonyl compounds, which are versatile organoboron reagents and could undergo various synthetic transformations. This efficient, regiospecific reaction showed good functional group tolerance and could be used for late-stage modification of structurally complex bioactive compounds.
创建时间：
2018-07-19
