Conversion of 2‑Furylcarbinols with Alkyl or Aryl Azides to Highly Functionalized 1,2,3-Triazoles via Cascade Formal [3 + 2] Cycloaddition/Ring-Opening
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https://figshare.com/articles/dataset/Conversion_of_2_Furylcarbinols_with_Alkyl_or_Aryl_Azides_to_Highly_Functionalized_1_2_3_Triazoles_via_Cascade_Formal_3_2_Cycloaddition_Ring_Opening/2249839
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资源简介：
A Lewis acid promoted cascade cycloaddition/ring-opening
of 2-furylcarbinols
with alkyl or aryl azides is described. The reaction features an initial
formal [3 + 2] cycloaddition to form a trisubstitued triazole motif,
followed by a ring opening of furan to generate the (E)-configuration of the enone. A wide range of highly functionalized
triazoles is expediently and efficiently synthesized in a highly step-economical
manner.
创建时间：
2016-02-16
