Oxidative Cleavage of the CN Bond on Al(I)
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https://figshare.com/articles/dataset/Oxidative_Cleavage_of_the_C_N_Bond_on_Al_I_/5132524
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资源简介：
Reaction of the cyclic guanidine TolNSIMe with the aluminum(I) compound NacNacAl (1) results in the unprecedented cleavage of the C–N multiple bond to give, after rearrangement, the carbene-ligated Al(III) amide, NacNac′Al(NHTol)(SIMe) (6). DFT calculations revealed that these reactions proceed via a bimolecular mechanism in which either the basic Al(I) center or the transient AlNTol species deprotonates the methyl group of the NacNac ligand.
创建时间：
2017-06-21
