Protic Ruthenium Tris(pyrazol-3-ylmethyl)amine Complexes Featuring a Hydrogen-Bonding Network in the Second Coordination Sphere
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https://figshare.com/articles/dataset/Protic_Ruthenium_Tris_pyrazol_3_ylmethyl_amine_Complexes_Featuring_a_Hydrogen_Bonding_Network_in_the_Second_Coordination_Sphere/2096788
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资源简介：
We synthesized ruthenium complexes
bearing a tris(pyrazol-3-ylmethyl)amine ligand LH3 and
revealed that this tripodal ligand allows predictable accumulation
of three proton-delivering NH groups around a coordination site. The
Brønsted acidity of the NH groups in LH3 led to the
formation of multiple hydrogen bonds with the substrate ligand and
deprotonation. The chlorido complex ligated by LH3 catalyzed
disproportionation of 1,2-diphenylhydrazine.
创建时间：
2016-02-12
