Supplementary information files for "Metal-organic frameworks of p-hydroxybenzoic acid: synthesis, structure and ring-opening polymerization capability."
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https://repository.lboro.ac.uk/articles/dataset/Supplementary_information_files_for_Metal-organic_frameworks_of_p-hydroxybenzoic_acid_synthesis_structure_and_ring-opening_polymerization_capability_/28912214
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Supplementary files for article "Metal-organic frameworks of p-hydroxybenzoic acid: synthesis, structure and ring-opening polymerization capability."<br><br>Two new, isostructural, metal–organic frameworks {[Co(O<sub>2</sub>CC<sub>6</sub>H<sub>4</sub>O)(DMF)]<sub>2</sub>}<sub><em>n</em></sub> and {[Mn(O<sub>2</sub>CC<sub>6</sub>H<sub>4</sub>O)(DMF)]<sub>2</sub>}<sub><em>n</em></sub> have been synthesised and structurally characterized. Use of <i>p</i>-hydroxybenzoic acid resulted in a three-dimensional MOF featuring a linker with a carboxylic group and a <i>para</i>-hydroxyl group. Ring opening polymerization of ε-caprolactone and δ-valerolactone has been performed using these MOFs as catalysts, and results compared with the known zinc MOF Zn(O<sub>2</sub>CC<sub>6</sub>H<sub>4</sub>O). The resulting products are predominantly cyclic polymers. The manganese and zinc MOFs exhibit significant recyclability during ring opening polymerization.<br><br>© The Author(s), CC BY-3.0 Unported license
提供机构：
Loughborough University
创建时间：
2025-05-01
