Syntheses, Structural Characterization, and Luminescence Behavior of Face-to-Face Diplatinum(II) Alkynyl Complexes
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https://figshare.com/articles/dataset/Syntheses_Structural_Characterization_and_Luminescence_Behavior_of_Face-to-Face_Diplatinum_II_Alkynyl_Complexes/3771702
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资源简介：
A series of luminescent face-to-face dinuclear platinum(II) alkynyl complexes, [Pt2(μ-dppm)2(C⋮CR)4] (R = C6H4-Cl-p, C6H4-NO2-p, SiMe3), and a mixed-metal platinum(II)−silver(I)
complex, [Pt2(μ-dppm)2(C⋮CPh)4·{Ag(MeCN)}2](BF4)2, were synthesized and characterized
by both spectroscopy and X-ray crystallography. Their luminescence behavior were studied
and the nature of the emission origin was elucidated by comparison studies involving the
perturbation of Pt···Pt distances as well as the π-accepting ability of the alkynyl group
through a systematic variation of the nature of the alkynyl moieties and metal ion
encapsulation.
创建时间：
2016-08-26
