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Diboran(4)yl Platinum(II) Complexes

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Diboran_4_yl_Platinum_II_Complexes/2396296
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The platinum diboran(4)­yl complexes 1–3 have been prepared by the selective oxidative addition of one B–Hal bond in aryl-substituted diboranes(4) Hal2B2Ar2 (Hal = Cl, Ar = mes, dur; Hal = I, Ar = mes). Because of the electron deficiency of the remote B2 atom, all species show a rare dative Pt–B bonding interaction, whose magnitude is strongly dependent on the nature of the halide substituent.
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2016-02-19
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