Anomalous Reactivity and Selectivity in the Intermolecular Diels–Alder Reactions of Multisubstituted Acyclic Dienes with Geometrical Isomers of Enals
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A Lewis-acid catalyzed intermolecular Diels–Alder reaction between multisubstituted acyclic dienes and the E and Z isomers of α,β-enals was studied. It was found that the diene reacted selectively with the Z-isomer of the α,β-enal.
创建时间:
2016-05-16



