Isoselective Living Polymerization of 1-Hexene Catalyzed by Half-Metallocene Dimethyl Complexes of Hafnium with Bidentate N-Substituted (Iminomethyl)pyrrolyl Ligands
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https://figshare.com/articles/dataset/Isoselective_Living_Polymerization_of_1_Hexene_Catalyzed_by_Half_Metallocene_Dimethyl_Complexes_of_Hafnium_with_Bidentate_N_Substituted_Iminomethyl_pyrrolyl_Ligands/3279271
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资源简介：
The nonbridged half-metallocene dimethylhafnium complexes 3a−c with N-substituted (iminomethyl)pyrrolyl ligands 2a−c have been synthesized and
characterized by NMR spectroscopy as well as X-ray
analyses for 3a,b. These complexes were found to be
active catalysts for the isoselective living polymerization
of 1-hexene upon treatment with [Ph3C][B(C6F5)4] below
0 °C.
创建时间：
2016-05-05
