Encapsulation and Sensitization of UV–vis and Near Infrared Lanthanide Hydrate Emitters for Dual- and Bimodal-Emissions in Both Air and Aqueous Media Based on a Porous Heteroatom-Rich Cd(II)-Framework
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https://figshare.com/articles/dataset/Encapsulation_and_Sensitization_of_UV_vis_and_Near_Infrared_Lanthanide_Hydrate_Emitters_for_Dual_and_Bimodal_Emissions_in_Both_Air_and_Aqueous_Media_Based_on_a_Porous_Heteroatom_Rich_Cd_II_Framework/2486392
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资源简介：
A porous heteroatom-rich Cd(II)-polymeric framework which
is generated
from an ethylene glycol ether-bridging dicarboxylate ligand L, 4,4′-bipy and Cd(II) ion is reported. It contains
one-dimensional tubes (9–11 Å) which are able to trap
cationic lanthanide hydrates such as Eu(H2O)83+, Tb(H2O)83+, and Nd(H2O)83+ under ambient conditions to generate
Ln(H2O)83+-loaded materials. In addition,
the heteroatom-rich host material can effectively protect and sensitize
the encapsulated Ln3+ emitters in their hydrate form in
both air and aqueous media. Furthermore, the dual- and bimodal-emissions
are successfully realized by intercalation of the different Ln3+-hydrates based on a guest-driven approach.
创建时间：
2012-09-17
