Hydrogen Polyphosphides P<sub>3</sub>H<sub>2</sub><sup>3−</sup> and P<sub>3</sub>H<sub>3</sub><sup>2−</sup>: Synthesis and Crystal Structure of K<sub>3</sub>(P<sub>3</sub>H<sub>2</sub>)·2.3NH<sub>3</sub>, Rb<sub>3</sub>(P<sub>3</sub>H<sub>2</sub>)·NH<sub>3</sub>, [Rb(18-crown-6)]<sub>2</sub>(P<sub>3</sub>H<sub>3</sub>)·7.5NH<sub>3</sub>, and [Cs(18-crown-6)]<sub>2</sub>(P<sub>3</sub>H<sub>3</sub>)·7NH<sub>3</sub>
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数据链接：
https://figshare.com/articles/dataset/Hydrogen_Polyphosphides_P_sub_3_sub_H_sub_2_sub_sup_3_sup_and_P_sub_3_sub_H_sub_3_sub_sup_2_sup_Synthesis_and_Crystal_Structure_of_K_sub_3_sub_P_sub_3_sub_H_sub_2_sub_2_3NH_sub_3_sub_Rb_sub_3_sub_P_sub_3_sub_H_sub_2_sub_NH_sub_3_sub_Rb_18_crown_6_sub_2_su/2874820数据链接链接失效反馈
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资源简介：
The incongruous solvation of polyphosphides and phosphanes or the direct reduction of white phosphorus in liquid ammonia leads to the hydrogen polyphosphides catena-dihydrogen triphosphide, P3H23−, and catena-trihydrogen triphosphide, P3H32−, in the crystalline compounds K3(P3H2)·2.3NH3 (1), Rb3(P3H2)·NH3 (2), [Rb(18-crown-6)]2(P3H3)·7.5NH3 (3), and [Cs(18-crown-6)]2(P3H3)·7NH3 (4).
创建时间：
2016-02-26
