Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor
收藏NIAID Data Ecosystem2026-03-06 收录
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The one-electron oxidation of tetramethoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially π-stacked conformer as established by (i) electrochemical analysis, (ii) by the observation of the intense charge-resonance transition in the near IR region in its cation radical spectrum, and (iii) by X-ray crystallographic characterization of the isolated cation radical salt (4+• SbCl6−).
创建时间：
2016-02-26
