Preparation of Stereodefined 2‑(3-Oxoindolin-2-yl)-2-Arylacetonitriles via One-Pot Reaction of Indoles with Nitroalkenes
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https://figshare.com/articles/dataset/Preparation_of_Stereodefined_2_3-Oxoindolin-2-yl_-2-Arylacetonitriles_via_One-Pot_Reaction_of_Indoles_with_Nitroalkenes/9867617
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Recently discovered reactivity of nitrostyrenes in phosphorous acid to facilitate the diastereoselective [4 + 1]-cycloaddition of indoles in combination with unusual oxazoline ring cleavage and subsequent 1,2-alkyl shift afforded stereochemically defined 2-(3-oxoindolin-2-yl)-2-arylacetonitriles as sole products.
创建时间：
2019-09-10
