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Formation of Ethylene-Bridged Dinuclear Ir<sup>III</sup> Species via M−C Coupling of Ir<sup>II</sup> and Ir<sup>II</sup>(ethene)

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NIAID Data Ecosystem2026-03-06 收录
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Ethene dissociation from [(Mentpa)IrII(ethene)]2+, induced by coordination of acetonitrile, causes a rapid and selective M−C coupling between IrII and IrII(ethene), resulting in ethylene-bridged dinuclear iridium(III) complexes of the composition [{(Mentpa)IrIII(NCMe)}2(μ2-C2H4)]4+ (n = 2, 3).

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2016-08-26
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