Intense Near-Infrared Optical Absorbing Emerald Green [60]Fullerenes

Synthesis of emerald green fullerenes (EF) C60[C(CH3)(CO2Et)2]6 and C60[C(CH3)(CO2-t-Bu)2]6 was performed by using hexaanionic C60 intermediate (C60-6) as a reagent in one-pot reaction for attaching six alkyl ester addends on one C60 cage. These EF compounds exhibit intense optical absorption over 600−940 nm, the longest optical absorption of the C60 cage among many [60]fullerene derivatives synthesized.